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Cheese Making Ingredients, Calcium Chloride

Calcium & Milk

Milk can have different rennet coagulation abilities and this can be caused mainly by different particle sizes of casein, the main protein in milk. The higher the milk’s content of calcium, the bigger the casein particles will be. The bigger the particles are, the better the coagulation ability of the milk. Secondarily, casein particle size also influences the ease by which cheese curds shrink and releases whey. If the casein particle size is big, the network is open and coarse, and whey drains more readily.

Different factors influence the calcium content of milk:

  • Milk that is stored at low temperatures releases calcium. Thus the pasteurization process of heating and then rapidly cooling milk reduces calcium.
  • Late lactation season milk has low calcium.
  • Milk from diseased animals has low calcium.

To compensate for precipitation of calcium, calcium chloride is frequently added to milk as it is effective, low cost, and has long shelf life.

Calcium Chloride Properties

Calcium Chloride (chemical formula CaCl2) is a salt compound of one calcium and two chloride atoms. It is highly soluble in water and is a deliquescent meaning that in dry form it has a strong affinity for moisture and if left unsealed, will absorb large amounts from the atmosphere and will in time form a liquid solution. CaCl2 is a common additive in the food making industry. Common uses are for salty taste in sports drinks, as a preservative and to maintain firmness in canned vegetables, especially pickles, and in cheese making primarily when using processed - pasteurized milk.

Calcium Chloride Availability

Food grade Calcium Chloride is available from Cheese Making Supply Stores in solution format. It is also available in highly refined form for use in salt water aquariums, but it is not known if those products are human food grade quality.

Note, if the salt (NaCl) content in the milk is too high, ion exchange occurs, so that the calcium is displaced from casein by sodium, which to some extent decreases the milks' coagulation ability. This is normally not a problem as salt is not normally added to cheese until after renneting - coagulation.

Additional Information

More information and discussion on Calcium Chloride for cheese making is available normally in CheeseForum.org's Forum Cheese Making - Ingredients Board or by searching the forum using the Search Box in top right corner.