Oooohhh, raw buffalo milk! You must be using a modified method, both starter and citric acid. Your yogurt could have more live culture in it, which would affect the amount of time it takes to drop pH. Or the raw milk has a few too many of its own bacteria, and got the process started before you received it. When my girls milk changes pH, I just gradually add the diluted acid a 1/4 tsp. and a time, until i reach the target pH. Anyone else have any ideas?